Silyl Ethers of Stannylated Hydroxymethylfurans and Bromopyrimidinones in Palladium-mediated Coupling Reactions.

Effect of fluorine on palladium-catalyzed cross-coupling reactions of aryl bromides with trifluoromethyl aryl ketones via difluoroenol silyl or monofluoroenol silyl ethers.

Palladium-catalyzed cross-coupling reactions of alpha-aryl-beta,beta-difluoroenol silyl and alpha-aryl-beta-fluoroenol silyl ethers with aryl bromides proceed smoothly with good functional compatibility.

Synthesis of novel tridentate ligand-based palladium catalyst and investigation of its reactivity towards Suzuki, Sonogashira and Heck coupling reactions

We have demonstrated a simple and efficient route for the synthesis of a novel imine based tridentate ligand and its Pd-complex to investigate the C-C cross-coupling reactions, that involve column chromatography purification in only one step. The catalytic activity of the newly synthesized catalyst was studied for the Suzuki, Sonogashira and, Heck cross-coupling reactions under mild conditions....

One-pot synthesis of tropinone by tandem (domino) ene-type reactions of acetone silyl enol ethers.

A synthetic approach for tropane alkaloids on the basis of tandem (domino) ene-type reactions of acetone silyl enol ethers with iminium ions is shown to be triggered by intermolecular ene-type reactions followed by 6-(2,5) silatropic ene-type cyclizations.

Gallium tribromide catalyzed coupling reaction of alkenyl ethers with ketene silyl acetals.

Palladium-catalyzed cross-coupling reactions in total synthesis.

In studying the evolution of organic chemistry and grasping its essence, one comes quickly to the conclusion that no other type of reaction plays as large a role in shaping this domain of science than carbon-carbon bond-forming reactions. The Grignard, Diels-Alder, and Wittig reactions are but three prominent examples of such processes, and are among those which have undeniably exercised decisi...